Long before Ben Affleck, Jennifer Garner was married to actor Scott Foley — the two met when Jen played Scott's out-of-town girlfriend on Felicity back in 1998, and they tied the knot for real in 2000. They stayed together for two-and-a-half years before divorcing, and Jennifer went on to date her Alias co-star Michael Vartan. We all know what happened after that.
Jennifer Garner and Scott Foley
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